Tetrachlorido(1,10-phenanthroline-κ2 N,N′)platinum(IV) acetonitrile hemisolvate
نویسندگان
چکیده
The asymmetric unit of the title compound, [PtCl(4)(C(12)H(8)N(2))]·0.5CH(3)CN, contains two crystallographically independent Pt(IV) complexes with very similar geometry and one solvent mol-ecule. In the complexes, each Pt(IV) ion is six-coordinated in a distorted octa-hedral environment by two N atoms of the 1,10-phenanthroline ligand and four Cl atoms. Because of the different trans effects of the N and Cl atoms, the Pt-Cl bonds trans to the N atom are slightly shorter than those trans to the Cl atom. The compound displays numerous inter-molecular π-π inter-actions between six-membered rings, with a shortest centroid-to-centroid distance of 3.654 Å. There are also weak intra- and inter-molecular C-H⋯Cl hydrogen bonds.
منابع مشابه
Bis(acetonitrile-κN)(1,10-phenanthroline-κ2 N,N′)platinum(II) bis(perchlorate)
The asymmetric unit of the title compound, [Pt(CH(3)CN)(2)(C(12)H(8)N(2))](ClO(4))(2), contains one half of a cationic Pt(II) complex and pair of half perchlorate anions, one of which is disordered over two sites in a 0.53 (3):0.47 (3) ratio. The complex and anions are disposed about a crystallographic mirror plane parallel to the ac plane passing through the Pt and Cl atoms. In the complex, th...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009